15 Real-Life Celeb Couples Who Fell in Love on Set

Though they didn’t publicly step out as a couple until the spring of 2005 – a few months after he announced his split from wife Jennifer Aniston – Angelina Jolie and Brad Pitt both later admitted that they fell in love on the 2004 set of “Mr. & Mrs. Smith.” The parents of six tied the knot in 2014. Angie filed for divorce two years later.

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